LBOI
Landolt-Boernstein Search
  Home  |   Search  |   Indices  |   Indexed Volumes  
scidex

CAS Number


 

European regulations regarding Arsenate(3-), dihydrogen-d2- (AsD2O4Rb)

This Compound in the Landolt-Börnstein Index
Structure Drawing Formula:AsD2O4Rb
Molecular Weight:228.417 g/mol
NameArsenate(3-), dihydrogen-d2-
CAS-RN16468-47-6
EG-Index:033-005-00-1 (2009/2/EC)

Hazard Information (Dangerous Substances Directive 67/548/EEC)

Hazard symbols
  
T
Toxic
N
Dangerous for the Environment
2009/2/EC
R-Phrase45-23/25-50/53
R45 May cause cancer.
R23/25 Toxic by inhalation and if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2009/2/EC
S-Phrase53-45-60-61
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
2009/2/EC

GHS classification (Globally Harmonized System)
Regulation on Classification, Labelling and Packaging of Substances and Mixtures (CLP)

Signal WordDangerEC/1272/2008
Pictogram     
Hazard Statements
H350May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H331Toxic if inhaled.
H301Toxic if swallowed.
H410Very toxic to aquatic life with long lasting effects.
Precautionary Statements
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash ... thoroughly after handling.
P270Do no eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P281Use personal protective equipment as required.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308+P313IF exposed or concerned: Get medical advice/attention.
P311Call a POISON CENTER or doctor/physician.
P321Specific treatment (see ... on this label).
P330Rinse mouth.
P391Collect spillage.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to ...
ClassificationCarc. 1A
Acute Tox. 3 *
Acute Tox. 3 *
Aquatic Acute 1
Aquatic Chronic 1
EC-Reference033-005-00-1 

Registration, Evaluation, Authorisation and Restriction of CHemicals (REACH)

REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/19)EC/552/2009
       Entry19. Arsenic compounds
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
1. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use to prevent the fouling by micro-organisms, plants or animals of
- the hulls of boats,
- cages, floats, nets and any other appliances or equipment used for fish or shellfish farming,
- any totally or partly submerged appliances or equipment.
2. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use in the treatment of industrial waters, irrespective of their use.
3. Shall not be used in the preservation of wood. Furthermore, wood so treated shall not be placed on the market.
4. By way of derogation from paragraph 3
(a) Relating to the substances and mixtures for the preservation of wood: these may only be used in industrial installations using vacuum or pressure to impregnate wood if they are solutions of inorganic compounds of the copper, chromium, arsenic (CCA) type C and if they are authorised in accordance with Article 5(1) of Directive 98/8/EC. Wood so treated shall not be placed on the market before fixation of the preservative is completed.
(b) Wood treated with CCA solution in accordance with point (a) may be placed on the market for professional and industrial use provided that the structural integrity of the wood is required for human or livestock safety and skin contact by the general public during its service life is unlikely
- as structural timber in public and agricultural buildings, office buildings, and industrial premises,
- in bridges and bridgework,
- as constructional timber in freshwater areas and brackish waters, for example jetties and bridges,
- as noise barriers,
- in avalanche control,
- in highway safety fencing and barriers,
- as debarked round conifer livestock fence posts,
- in earth retaining structures,
- as electric power transmission and telecommunications poles,
- as underground railway sleepers.
(c) Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that all treated wood placed on the market is individually labelled “For professional and industrial installation and use only, contains arsenic”. In addition, all wood placed on the market in packs shall also bear a label stating "Wear gloves when handling this wood. Wear a dust mask and eye protection when cutting or otherwise crafting this wood. Waste from this wood shall be treated as hazardous by an authorised undertaking".
(d) Treated wood referred to under point (a) shall not be used
- in residential or domestic constructions, whatever the purpose,
- in any application where there is a risk of repeated skin contact,
- in marine waters,
- for agricultural purposes other than for livestock fence posts and structural uses in accordance with point (b),
- in any application where the treated wood may come into contact with intermediate or finished products intended for human and/or animal consumption.
5. Wood treated with arsenic compounds that was in use in the Community before 30 September 2007, or that was placed on the market in accordance with paragraph 4 may remain in place and continue to be used until it reaches the end of its service life.
6. Wood treated with CCA type C that was in use in the Community before 30 September 2007, or that was placed on the market in accordance with paragraph 4
- may be used or reused subject to the conditions pertaining to its use listed under points 4(b), (c) and (d),
- may be placed on the market subject to the conditions pertaining to its use listed under points 4(b), (c) and (d).
7. Member States may allow wood treated with other types of CCA solutions that was in use in the Community before 30 September 2007
- to be used or reused subject to the conditions pertaining to its use listed under points 4 (b), (c) and (d),
- to be placed on the market subject to the conditions pertaining to its use listed under points 4(b), (c) and (d).
REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/28)EC/552/2009
       Entry28. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as carcinogen category 1A or 1B (Table 3.1) or carcinogen category 1 or 2 (Table 3.2)
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Without prejudice to the other parts of this Annex the following shall apply to entries 28 to 30
1. Shall not be placed on the market, or used,
- as substances,
- as constituents of other substances, or,
- in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than
- either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
- the relevant concentration specified in Directive 1999/45/EC.
Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of such substances and mixtures is marked visibly, legibly and indelibly as follows
'Restricted to professional users'.
2. By way of derogation, paragraph 1 shall not apply to
(a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC;
(b) cosmetic products as defined by Directive 76/768/EEC;
(c) the following fuels and oil products
- motor fuels which are covered by Directive 98/70/EC,
- mineral oil products intended for use as fuel in mobile or fixed combustion plants,
- fuels sold in closed systems (e.g. liquid gas bottles);
(d) artists' paints covered by Directive 1999/45/EC.

References

2009/2/EC
Short: 2009/2/EC
Title: COMMISSION DIRECTIVE 2009/2/EC of 15 January 2009 amending, for the purpose of its adaptation to technical progress, for the 31st time, Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances
Author: Comission of the European Communities
Source: Official Journal of the European Communities
Volume: L 11 (16.01.2009)
Page: 6-82
Year: 2009
Keyword: hazardous materials; hazard classification
Publish_Date: 2009/01/16
EC/1272/2008
Short: EC/1272/2008
Title: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 353 (31.12.2008)
Page: 1-1355
Year: 2008
Publish_Date: 2008/12/31
EC/552/2009
Short: EC/552/2009
Title: COMMISSION REGULATION (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XVII
Author: Commission of the European Communities
Source: Official Journal of the European Union
Volume: L 164 (26.06.2009)
Page: 7-31
Year: 2009
Keyword: Registration, Evaluation, Authorisation and Restriction of Chemicals; placing on the market
Publish_Date: 2009/06/26

  File created on 2009/18/08 by LCI Publisher GmbH (Gaja Peters, Inga Thede, Volkmar Vill, Ron Zenczykowski)
  © 2009   Landolt Börnstein,   Springer-Verlag Berlin Heidelberg