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European regulations regarding Piperazine (C4H10N2)

This Compound in the Landolt-Börnstein Index
Structure Drawing Formula:C4H10N2
Molecular Weight:86.136 g/mol
NamePiperazine
CAS-RN110-85-0
EG-Index:612-057-00-4 (2008/58/EC)
EINECS:203-808-3 (EINECS)

Hazard Information (Dangerous Substances Directive 67/548/EEC)

Hazard symbols
  
C
Corrosive
Xn
Harmful
2008/58/EC
R-Phrase34-42/43-62-63
R34 Causes burns.
R42/43 May cause sensitization by inhalation and skin contact.
R62 Possible risk of impaired fertility.
R63 Possible risk of harm to the unborn child.
2008/58/EC
S-Phrase(1/2-)23-26-36/37/39-45
S1/2 Keep locked up and out of the reach of children.
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2008/58/EC

GHS classification (Globally Harmonized System)
Regulation on Classification, Labelling and Packaging of Substances and Mixtures (CLP)

Signal WordDangerEC/1272/2008
Pictogram   
Hazard Statements
H314Causes severe skin burns and eye damage.
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317May cause an allergic skin reaction.
H412Harmful to aquatic life with long lasting effects.
Precautionary Statements
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash ... thoroughly after handling.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P285In case of inadequate ventilation wear respiratory protection.
P301+P330+P331IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see ... on this label).
P333+P313If skin irritation or rash occurs: Get medical advice/attention.
P342+P311If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container to ...
ClassificationSkin Corr. 1B
Resp. Sens. 1
Skin Sens. 1
Aquatic Chronic 3
EC-Reference612-057-00-4 

European CHemicals Agency (ECHA) pre-registration

Pre-registered substanceEC-Number: 203-808-3
CAS-Number: 110-85-0
Name: piperazine
Synonym: -
Registration Date: 30/11/2010
ECHA pre

References

2008/58/EC
Short: 2008/58/EC
Title: COMMISSION DIRECTIVE 2008/58/EC of 21 August 2008 amending, for the purpose of its adaptation to technical progress, for the 30th time, Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances
Author: Comission of the European Communities
Source: Official Journal of the European Communities
Volume: L 246 (15.09.2008)
Page: 1-246
Year: 2008
Keyword: hazardous materials; hazard classification
Publish_Date: 2008/09/15
EC/1272/2008
Short: EC/1272/2008
Title: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 353 (31.12.2008)
Page: 1-1355
Year: 2008
Publish_Date: 2008/12/31
ECHA pre
Short: ECHA pre
Title: List of pre-registered substances
Author: European Chemicals Agency
Year: 2009

  File created on 2009/18/08 by LCI Publisher GmbH (Gaja Peters, Inga Thede, Volkmar Vill, Ron Zenczykowski)
  © 2009   Landolt Börnstein,   Springer-Verlag Berlin Heidelberg