LBOI
Landolt-Boernstein Search
  Home  |   Search  |   Indices  |   Indexed Volumes  
scidex

Chemical Name


 

European regulations regarding 2-methylbenzenamine (C7H9N)

This Compound in the Landolt-Börnstein Index
Structure Drawing Formula:C7H9N
Molecular Weight:107.153 g/mol
Name2-methylbenzenamine
CAS-RN95-53-4
EG-Index:612-091-00-X (96/54/EC)
EINECS:202-429-0 (EINECS)

Hazard Information (Dangerous Substances Directive 67/548/EEC)

Hazard symbols
  
T
Toxic
N
Dangerous for the Environment
96/54/EC
R-Phrase45-23/25-36-50
R45 May cause cancer.
R23/25 Toxic by inhalation and if swallowed.
R36 Irritating to eyes.
R50 Very toxic to aquatic organisms.
96/54/EC
S-Phrase53-45-61
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
96/54/EC

GHS classification (Globally Harmonized System)
Regulation on Classification, Labelling and Packaging of Substances and Mixtures (CLP)

Signal WordDangerEC/1272/2008
Pictogram     
Hazard Statements
H350May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H331Toxic if inhaled.
H301Toxic if swallowed.
H319Causes serious eye irritation.
H400Very toxic to aquatic life.
Precautionary Statements
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash ... thoroughly after handling.
P270Do no eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
P311Call a POISON CENTER or doctor/physician.
P321Specific treatment (see ... on this label).
P330Rinse mouth.
P337+P313If eye irritation persists: Get medical advice/attention.
P391Collect spillage.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to ...
ClassificationCarc. 1B
Acute Tox. 3 *
Acute Tox. 3 *
Eye Irrit. 2
Aquatic Acute 1
EC-Reference612-091-00-X 

Registration, Evaluation, Authorisation and Restriction of CHemicals (REACH)

REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/43)EC/552/2009
       Entry43. Azocolourants and Azodyes
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
1. Azodyes which, by reductive cleavage of one or more azo groups, may release one or more of the aromatic amines listed in Appendix 8, in detectable concentrations, i.e. above 30 mg/kg (0,003 % by weight) in the articles or in the dyed parts thereof, according to the testing methods listed in Appendix 10, shall not be used, in textile and leather articles which may come into direct and prolonged contact with the human skin or oral cavity, such as
- clothing, bedding, towels, hairpieces, wigs, hats, nappies and other sanitary items, sleeping bags,
- footwear, gloves, wristwatch straps, handbags, purses/wallets, briefcases, chair covers, purses worn round the neck,
- textile or leather toys and toys which include textile or leather garments,
- yarn and fabrics intended for use by the final consumer.
2. Furthermore, the textile and leather articles referred to in paragraph 1 shall not be placed on the market unless they conform to the requirements set out in that paragraph.
3. Azodyes, which are contained in Appendix 9, 'List of azodyes' shall not be placed on the market, or used, as substances, or in mixtures in concentrations greater than 0,1 % by weight, where the substance or the mixture is intended for colouring textile and leather articles.
REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/28)EC/552/2009
       Entry28. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as carcinogen category 1A or 1B (Table 3.1) or carcinogen category 1 or 2 (Table 3.2)
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Without prejudice to the other parts of this Annex the following shall apply to entries 28 to 30
1. Shall not be placed on the market, or used,
- as substances,
- as constituents of other substances, or,
- in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than
- either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
- the relevant concentration specified in Directive 1999/45/EC.
Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of such substances and mixtures is marked visibly, legibly and indelibly as follows
'Restricted to professional users'.
2. By way of derogation, paragraph 1 shall not apply to
(a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC;
(b) cosmetic products as defined by Directive 76/768/EEC;
(c) the following fuels and oil products
- motor fuels which are covered by Directive 98/70/EC,
- mineral oil products intended for use as fuel in mobile or fixed combustion plants,
- fuels sold in closed systems (e.g. liquid gas bottles);
(d) artists' paints covered by Directive 1999/45/EC.

European CHemicals Agency (ECHA) pre-registration

Pre-registered substanceEC-Number: 202-429-0
CAS-Number: 95-53-4
Name: o-toluidine
Synonym: -
Registration Date: 30/11/2010
ECHA pre

References

96/54/EC
Short: 96/54/EC
Title: Commission Directive 96/54/EC of 30 July 1996 adapting to technical progress for the twenty-second time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances
Author: Comission of the European Communities
Source: Official Journal of the European Communities
Volume: L 248 (30.09.1996)
Page: 1-230
Year: 1996
Keyword: hazardous materials; hazard classification
Publish_Date: 1996/09/30
EC/1272/2008
Short: EC/1272/2008
Title: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 353 (31.12.2008)
Page: 1-1355
Year: 2008
Publish_Date: 2008/12/31
EC/552/2009
Short: EC/552/2009
Title: COMMISSION REGULATION (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XVII
Author: Commission of the European Communities
Source: Official Journal of the European Union
Volume: L 164 (26.06.2009)
Page: 7-31
Year: 2009
Keyword: Registration, Evaluation, Authorisation and Restriction of Chemicals; placing on the market
Publish_Date: 2009/06/26
ECHA pre
Short: ECHA pre
Title: List of pre-registered substances
Author: European Chemicals Agency
Year: 2009

  File created on 2009/18/08 by LCI Publisher GmbH (Gaja Peters, Inga Thede, Volkmar Vill, Ron Zenczykowski)
  © 2009   Landolt Börnstein,   Springer-Verlag Berlin Heidelberg