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Chemical Name


 

European regulations regarding 2-butenal (C4H6O)

This Compound in the Landolt-Börnstein Index
Structure Drawing Formula:C4H6O
Molecular Weight:70.09 g/mol
Name2-butenal
CAS-RN4170-30-3
EG-Index:605-009-00-9 (2001/59/EC)
EINECS:224-030-0 (EINECS)

Hazard Information (Dangerous Substances Directive 67/548/EEC)

Hazard symbols
   
T+
Very toxic
F
Highly flammable
N
Dangerous for the Environment
2001/59/EC
R-Phrase11-24/25-26-37/38-41-48/22-50-68
R11 Highly Flammable.
R24/25 Toxic in contact with skin and if swallowed.
R26 Very toxic by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R68/20)
2001/59/EC
S-Phrase(1/2-)26-28-36/37/39-45-61
S1/2 Keep locked up and out of the reach of children.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
2001/59/EC

GHS classification (Globally Harmonized System)
Regulation on Classification, Labelling and Packaging of Substances and Mixtures (CLP)

Signal WordDangerEC/1272/2008
Pictogram         
Hazard Statements
H225Highly flammable liquid and vapour.
H341Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H330Fatal if inhaled.
H311Toxic in contact with skin.
H301Toxic if swallowed.
H373May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H335May cause respiratory irritation.
H315Causes skin irritation.
H318Causes serious eye damage.
H400Very toxic to aquatic life.
Precautionary Statements
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P210Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash ... thoroughly after handling.
P270Do no eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P284Wear respiratory protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
P310Immediately call a POISON CENTER or doctor/physician.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P314Get medical advice/attention if you feel unwell.
P320Specific treatment is urgent (see ... on this label).
P321Specific treatment (see ... on this label).
P322Specific measures (see ... on this label).
P330Rinse mouth.
P332+P313If skin irritation occurs: Get medical advice/attention.
P361Remove/Take off immediately all contaminated clothing.
P362Take off contaminated clothing and wash before reuse.
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use ...for extinction.
P391Collect spillage.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to ...
ClassificationFlam. Liq. 2
Muta. 2
Acute Tox. 2 *
Acute Tox. 3 *
Acute Tox. 3 *
STOT RE 2 *
STOT SE 3
Skin Irrit. 2
Eye Dam. 1
Aquatic Acute 1
EC-Reference605-009-00-9 

Registration, Evaluation, Authorisation and Restriction of CHemicals (REACH)

REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/3)EC/552/2009
       Entry3. Liquid substances or mixtures, which are regarded as dangerous according to the definitions in Council Directive 67/548/EEC and Directive 1999/45/EC.
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
1. Shall not be used in
- ornamental articles, intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects.
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent unless required for fiscal reasons or perfume or both and if they
- present an aspiration hazard and are labelled with R65 or H304, and,
- can be used as fuel in decorative lamps, and,
- are packaged in containers of a capacity of 15 litres or less.
4. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of substances and mixtures covered by paragraph 3, where intended for use in lamps, is marked visibly, legibly and indelibly as follows
'Keep lamps filled with this liquid out of the reach of children'
REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/40)EC/552/2009
       Entry40. Substances meeting the criteria of flammability in Directive 67/548/EEC and classified as flammable, highly flammable or extremely flammable regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not.
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following
- metallic glitter intended mainly for decoration,
- artificial snow and frost,
- 'whoopee' cushions,
- silly string aerosols,
- imitation excrement,
- horns for parties,
- decorative flakes and foams,
- artificial cobwebs,
- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with
'For professional users only'.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of Council Directive 75/324/EEC
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated.

European CHemicals Agency (ECHA) pre-registration

Pre-registered substanceEC-Number: 224-030-0
CAS-Number: 4170-30-3
Name: crotonaldehyde
Synonym: -
Registration Date: 30/11/2010
ECHA pre

References

2001/59/EC
Short: 2001/59/EC
Title: Commission Directive 2001/59/EC of 6 August 2001 adapting to technical progress for the 28th time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances
Author: Comission of the European Communities
Source: Official Journal of the European Communities
Volume: L 225 (21.08.2001)
Page: 1-333
Year: 2001
Keyword: hazardous materials; hazard classification
Publish_Date: 2001/08/21
EC/1272/2008
Short: EC/1272/2008
Title: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 353 (31.12.2008)
Page: 1-1355
Year: 2008
Publish_Date: 2008/12/31
EC/552/2009
Short: EC/552/2009
Title: COMMISSION REGULATION (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XVII
Author: Commission of the European Communities
Source: Official Journal of the European Union
Volume: L 164 (26.06.2009)
Page: 7-31
Year: 2009
Keyword: Registration, Evaluation, Authorisation and Restriction of Chemicals; placing on the market
Publish_Date: 2009/06/26
ECHA pre
Short: ECHA pre
Title: List of pre-registered substances
Author: European Chemicals Agency
Year: 2009

  File created on 2009/18/08 by LCI Publisher GmbH (Gaja Peters, Inga Thede, Volkmar Vill, Ron Zenczykowski)
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