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European regulations regarding Cadmiumsulfid (CdS)

This Compound in the Landolt-Börnstein Index
Structure Drawing Formula:CdS
Molecular Weight:144.465 g/mol
NameCadmiumsulfid
CAS-RN1306-23-6
EG-Index:048-010-00-4 (2004/73/EC)
EINECS:215-147-8 (EINECS)

Hazard Information (Dangerous Substances Directive 67/548/EEC)

Hazard symbols
  
T
Toxic
N
Dangerous for the Environment
2004/73/EC
R-Phrase45-22-48/23/25-62-63-68-53
R45 May cause cancer.
R22 Harmful if swallowed.
R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R62 Possible risk of impaired fertility.
R63 Possible risk of harm to the unborn child.
R68/20)
R53 May cause long-term adverse effects in the aquatic environment.
2004/73/EC
S-Phrase53-45-61
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
2004/73/EC

GHS classification (Globally Harmonized System)
Regulation on Classification, Labelling and Packaging of Substances and Mixtures (CLP)

Signal WordDangerEC/1272/2008
Pictogram   
Hazard Statements
H350May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H341Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H361fdSuspected of damaging fertility. Suspected of damaging the unborn child.
H372Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H302Harmful if swallowed.
H413May cause long lasting harmful effects to aquatic life.
Precautionary Statements
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash ... thoroughly after handling.
P270Do no eat, drink or smoke when using this product.
P273Avoid release to the environment.
P281Use personal protective equipment as required.
P301+P312IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308+P313IF exposed or concerned: Get medical advice/attention.
P314Get medical advice/attention if you feel unwell.
P330Rinse mouth.
P405Store locked up.
P501Dispose of contents/container to ...
ClassificationCarc. 1B
Muta. 2
Repr. 2
STOT RE 1
Acute Tox. 4 *
Aquatic Chronic 4
EC-Reference048-010-00-4 

Registration, Evaluation, Authorisation and Restriction of CHemicals (REACH)

REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/23)EC/552/2009
       Entry23. Cadmium, CAS-Nr. 7440-43-9, EG-Nr. 231-152-8 and its compounds
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
For the purpose of this entry, the codes and chapters indicated in square brackets are the codes and chapters of the tariff and statistical nomenclature of Common Customs Tariff as established by Council Regulation (EEC) No 2658/87
1. Shall not be used to give colour to articles manufactured from the following substances and mixtures
(a) - polyvinyl chloride (PVC) [3904 10] [3904 21] [3904 22]
- polyurethane (PUR) [3909 50]
- low-density polyethylene (ld PE), with the exception of low-density polyethylene used for the production of coloured masterbatch [3901 10]
- cellulose acetate (CA) [3912 11] [3912 12]
- cellulose acetate butyrate (CAB) [3912 11] [3912 12]
- epoxy resins [3907 30]
- melamine — formaldehyde (MF) resins [3909 20]
- urea — formaldehyde (UF) resins [3909 10]
- unsaturated polyesters (UP) [3907 91]
- polyethylene terephthalate (PET) [3907 60]
- polybutylene terephthalate (PBT)
- transparent/general-purpose polystyrene [3903 11] [3903 19]
- acrylonitrile methylmethacrylate (AMMA)
- cross-linked polyethylene (VPE)
- high-impact polystyrene
- polypropylene (PP) [3902 10]
(b) paints [3208] [3209]
However, if the paints have a high zinc content, their residual concentration of cadmium shall be as low as possible and shall in any event be less than 0,1 % by weight.
In any case, whatever their use or intended final purpose, articles or components of articles manufactured from the substances and mixtures listed above coloured with cadmium shall not be placed on the market if their cadmium content (expressed as Cd metal) is greater than 0,01 % by weight of the plastic material.
2. However, paragraph 1 shall not apply to articles to be coloured for safety reasons.
3. Shall not be used to stabilise the following mixtures or articles manufactured from polymers or copolymers of vinyl chloride
- packaging materials (bags, containers, bottles, lids) [3923 29 10],
- office or school supplies [3926 10],
- fittings for furniture, coachwork or the like [3926 30],
- articles of apparel and clothing accessories (including gloves) [3926 20],
[...]
In any case, whatever their use or intended final purpose, the placing on the market of the above mixtures, articles or components of articles manufactured from polymers or copolymers of vinyl chloride, stabilised by substances containing cadmium is prohibited, if their cadmium content (expressed as Cd metal) exceeds 0,01 % by weight of the polymer.
4. However, paragraph 3 shall not apply to mixtures and articles using cadmium-based stabilisers for safety reasons.
5. For the purpose of this entry, "cadmium plating" means any deposit or coating of metallic cadmium on a metallic surface.
Shall not be used for cadmium plating metallic articles or components of the articles used in the following sectors/applications
(a) equipment and machinery for
[...]
In any case, whatever their use or intended final purpose, the placing on the market of cadmium-plated articles or components of such articles used in the sectors/applications listed in points (a) and (b) above and of articles manufactured in the sectors listed in point (b) above is prohibited.
6. The provisions referred to in paragraph 5 shall also be applicable to cadmium-plated articles or components of such articles when used in the sectors/applications listed in points (a) and (b) below and to articles manufactured in the sectors listed in (b) below
(a) equipment and machinery for the production of
[...]
7. However, the restrictions in paragraphs 5 and 6 shall not apply to
- articles and components of the articles used in the aeronautical, aerospace, mining, offshore and nuclear sectors whose applications require high safety standards and in safety devices in road and agricultural vehicles, rolling stock and vessels,
- electrical contacts in any sector of use, where that is necessary to ensure the reliability required of the apparatus on which they are installed.
REACH: restrictions on the manufacture, placing on the market and use (Annex XVII/28)EC/552/2009
       Entry28. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as carcinogen category 1A or 1B (Table 3.1) or carcinogen category 1 or 2 (Table 3.2)
       TextAnnex XVII: Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Without prejudice to the other parts of this Annex the following shall apply to entries 28 to 30
1. Shall not be placed on the market, or used,
- as substances,
- as constituents of other substances, or,
- in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than
- either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
- the relevant concentration specified in Directive 1999/45/EC.
Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of such substances and mixtures is marked visibly, legibly and indelibly as follows
'Restricted to professional users'.
2. By way of derogation, paragraph 1 shall not apply to
(a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC;
(b) cosmetic products as defined by Directive 76/768/EEC;
(c) the following fuels and oil products
- motor fuels which are covered by Directive 98/70/EC,
- mineral oil products intended for use as fuel in mobile or fixed combustion plants,
- fuels sold in closed systems (e.g. liquid gas bottles);
(d) artists' paints covered by Directive 1999/45/EC.

European CHemicals Agency (ECHA) pre-registration

Pre-registered substanceEC-Number: 215-147-8
CAS-Number: 1306-23-6
Name: cadmium sulphide
Synonym: -
Registration Date: 30/11/2010
ECHA pre

Restriction of the use of certain Hazardous Substances (RoHS)

Restriction of the use in electrical and electronic equipmentRoHS
       EntryCadmium
       Textexempted
8. Cadmium and its compounds in electrical contacts and cadmium plating except for applications banned under Directive 91/338/EEC amending Directive 76/769/EEC relating to restrictions on the marketing and use of certain dangerous substances and preparations.
13. Lead and cadmium in optical and filter glass.
21. Lead and cadmium in printing inks for the application of enamels on borosilicate glass.
30. Cadmium alloys as electrical/mechanical solder joints to electrical conductors located directly on the voice coil in transducers used in high-powered loudspeakers with sound pressure levels of 100 dB (A) and more.
35. Cadmium in photoresistors for optocouplers applied in professional audio equipment until 31 December 2009.
38. Cadmium and cadmium oxide in thick film pastes used on aluminium bonded beryllium oxide.

References

2004/73/EC
Short: 2004/73/EC
Title: COMMISSION DIRECTIVE 2004/73/EC of 29 April 2004 adapting to technical progress for the 29th time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances
Author: Comission of the European Communities
Source: Official Journal of the European Communities
Volume: L 152 (30.04.2004)
Page: 1-311
Year: 2004
Erratum_Source: Official Journal of the European Communities L 216 (16.06.2004) 1-310
Keyword: hazardous materials; hazard classification
Publish_Date: 2004/04/30
EC/1272/2008
Short: EC/1272/2008
Title: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 353 (31.12.2008)
Page: 1-1355
Year: 2008
Publish_Date: 2008/12/31
EC/552/2009
Short: EC/552/2009
Title: COMMISSION REGULATION (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XVII
Author: Commission of the European Communities
Source: Official Journal of the European Union
Volume: L 164 (26.06.2009)
Page: 7-31
Year: 2009
Keyword: Registration, Evaluation, Authorisation and Restriction of Chemicals; placing on the market
Publish_Date: 2009/06/26
ECHA pre
Short: ECHA pre
Title: List of pre-registered substances
Author: European Chemicals Agency
Year: 2009
RoHS
Short: RoHS
Title: DIRECTIVE 2002/95/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 27 January 2003 on the restriction of the use of certain hazardous substances in electrical and electronic equipment
Author: European Parliament; Council of the European Union
Source: Official Journal of the European Union
Volume: L 37 (13.02.2003)
Page: 19-23
Year: 2003
Publish_Date: 2003/02/13

  File created on 2009/18/08 by LCI Publisher GmbH (Gaja Peters, Inga Thede, Volkmar Vill, Ron Zenczykowski)
  © 2009   Landolt Börnstein,   Springer-Verlag Berlin Heidelberg


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